Preheat the oven to 350°F (180°C). Grease and line two 8-inch round cake pans with parchment paper.
In a bowl, whisk together the flour, cocoa powder, baking soda, baking powder, and salt. Set aside. 190 g all-purpose flour, 50 g natural cocoa powder, 1 1/2 teaspoon baking soda, 1/2 teaspoon baking powder, 3/4 teaspoon salt
In a separate large bowl, whisk together the egg whites, sugars, sour cream, milk, oil, vinegar, and vanilla until combined. 3 large egg whites, 150 g granulated sugar, 100 g soft brown sugar, 120 g sour cream, 120 g whole milk, 55 g oil, 1 teaspoon apple cider vinegar, 1 teaspoon vanilla paste
Add half the dry ingredients to the wet ingredients and mix. Pour in the hot coffee along with the remaining dry ingredients and mix until just combined. Do not overmix. 180 g hot coffee
Divide the batter evenly between the prepared pans. Bake for approximately 25 minutes, until a skewer inserted into the center comes out clean.
Run a knife around the edges of each cake to loosen. Let them sit in their pans for 15 minutes, then carefully turn out onto a wire rack. Cool completely, about 1 hour, before frosting.